Homochiral metal organic framework withunh-topology
نویسندگان
چکیده
منابع مشابه
A homochiral metal-organic framework membrane for enantioselective separation.
For the first time, a homochiral metal-organic framework membrane was prepared for the enantioselective separation of important chiral compounds, especially chiral drug intermediates, which will allow for the potential development of a new, sustainable and highly efficient chiral separation technique.
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Four new homochiral metal-organic framework (MOF) isomers, [Zn(l-L(Cl))(Cl)](H(2)O)(2) (1), [Zn(l-L(Br))(Br)](H(2)O)(2) (2), [Zn(d-L(Cl))(Cl)](H(2)O)(2) (3), and [Zn(d-L(Br))(Br)](H(2)O)(2) (4) [L = 3-methyl-2-(pyridin-4-ylmethylamino)butanoic acid], have been synthesized by using a derivative of L-/D-valine and Zn(CH(3)COO)(2)·2H(2)O. A three-periodic lattice with a parallel 1D helical channel...
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Photocatalytic degradation of toxic organic compound in water, soil and air by semiconductor catalysts such as TiO2 and ZnO have received much attention over the last two decades. However, the low quantum yield, easy agglomeration and difficult post-separation of these inorganic catalysts limit their application for large-scale applications. Metal-organic frameworks (MOFs) are the latest class ...
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Photocatalytic degradation of toxic organic compound in water, soil and air by semiconductor catalysts such as TiO2 and ZnO have received much attention over the last two decades. However, the low quantum yield, easy agglomeration and difficult post-separation of these inorganic catalysts limit their application for large-scale applications. Metal-organic frameworks (MOFs) are the latest class ...
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The long, linear cobalt(III) bis(dicarbollide)based bis(isophthalic acid) anion was synthesized as a tetraphenylphosphonium salt in five steps from 8-iodo-closo1,2-C2B10H11. The solvothermal reaction between the anionic bis(isophthalic acid) linker and copper(II) nitrate in acidified DMF yielded single crystals. Despite the tendency for copper(II) and analogous linear tetraacids to form members...
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ژورنال
عنوان ژورنال: Acta Crystallographica Section A Foundations of Crystallography
سال: 2011
ISSN: 0108-7673
DOI: 10.1107/s0108767311081037